【前沿讲坛】Biomimetic Metal-Oxygen Intermediates in Dioxygen Activation Chemistry
讲座名称：
【前沿讲坛】Biomimetic Metal-Oxygen Intermediates in Dioxygen Activation Chemistry
讲座时间：
2019-11-25
讲座人：
Wonwoo Nam
形式：
校区：
兴庆校区
实践学分：
讲座内容：
讲座题目： Biomimetic Metal-Oxygen Intermediates in Dioxygen Activation Chemistry
讲座时间：2019年11月25日，下午4:00
讲座地点：西二楼 A102，曲江校区
讲座人：Wonwoo Nam
讲座简介：
Dioxygen is essential in life processes, and enzymes activate dioxygen to carry out a variety of biological reactions. One primary goal in biomimetic research is to elucidate structures of reactive intermediates and mechanistic details of dioxygen activation and oxygenation reactions occurring at the active sites of enzymes, by utilizing synthetic metal-oxygen complexes. A growing class of metal-oxygen complexes, such as metal–superoxo, –peroxo, –hydroperoxo, and –oxo species, have been isolated, characterized spectroscopically, and investigated in various oxygenation reactions. During the past decade, we have been studying the chemical and physical properties of various reactive intermediates in oxygenation reactions, such as high-valent metal-oxo complexes of heme and non-heme ligands in oxo-transfer and C-H activation reactions, non-heme metal-peroxo complexes in nucleophilic reactions, and non-heme metal-superoxo complexes in electrophilic reactions. The effects of supporting and axial ligands on structural and spectroscopic properties and reactivities of metal-oxygen adducts have been extensively investigated as well. In this presentation, I will present our recent results on the synthesis and structural and spectroscopic characterization of mononuclear nonheme metal-dioxygen intermediates as well as their reactivities in electrophilic and nucleophilic oxidation reactions.
相关视频