Cobalt-Catalyzed Hydrofunctionalization of Unsaturated Hydrocarbons
讲座名称：
Cobalt-Catalyzed Hydrofunctionalization of Unsaturated Hydrocarbons
讲座时间：
2019-06-12
讲座人：
GE Shaozhong
形式：
校区：
兴庆校区
实践学分：
讲座内容：
讲座题目：Cobalt-Catalyzed Hydrofunctionalization of Unsaturated Hydrocarbons
讲座人：Dr. GE Shaozhong, National University of Singapore, Assistant Professor
地点：西二楼 A102，曲江校区
时间：2019年6月12日，下午15:30
主办单位：前沿科学技术研究院
A major area of research focus in the Ge lab @ National University of Singapore (NUS) is the development of base metals (Fe, Co, Ni, and Cu) catalyzed hydroboration and hydrosilylation of unsaturated hydrocarbons to access synthetically versatile organosilanes and oragnoboron compounds, which are valuable reagents in organic synthesis due to their high stability and low toxicity. He will discuss a series of regio-, stereo-, or enantioselective cobalt-catalyzed hydroboration and hydrosilylation of alkenes, alkynes, allenes, enynes, and conjugated dienes (some recent examples are shown in the figure below). The catalysts for these hydrofunctionalization reactions are generated from readily available and bench-stable Co(acac)2 and bisphosphine ligands.
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